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Photochemical syntheses, transformations, and bioorthogonal chemistry of trans-cycloheptene and sila trans-cycloheptene Ag(i) complexes

A photochemical synthesis of AgNO(3) complexes of trans-cycloheptene (TCH) and trans-1-sila-4-cycloheptene (Si-TCH) derivatives is described. A low temperature flow photoreactor was designed to enable the synthesis of carbocyclic TCH derivatives due to their thermal sensitivity in the absence of met...

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Publicat a:Chem Sci
Autors principals: Fang, Yinzhi, Zhang, Han, Huang, Zhen, Scinto, Samuel L., Yang, Jeffrey C., am Ende, Christopher W., Dmitrenko, Olga, Johnson, Douglas S., Fox, Joseph M.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5892336/
https://ncbi.nlm.nih.gov/pubmed/29675242
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04773h
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