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Total Synthesis of Aurofusarin: Studies on the Atropisomeric Stability of Bis-Naphthoquinones
An efficient annulation involving pyrone addition to a quinone and Dieckmann condensation was developed for rapid assembly of a γ-naphthopyrone monomeric precursor to the bis-naphthoquinone natural product aurofusarin. Dimerization was achieved through Pd(II)-catalyzed dehydrogenative coupling. Furt...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5890919/ https://ncbi.nlm.nih.gov/pubmed/29318760 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201711535 |
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