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Regioselective Simmons–Smith-type cyclopropanations of polyalkenes enabled by transition metal catalysis
A [(i–Pr)PDI]CoBr(2) complex (PDI = pyridine-diimine) catalyzes Simmons–Smith-type reductive cyclopropanation reactions using CH(2)Br(2) in combination with Zn. In contrast to its non-catalytic variant, the cobalt-catalyzed cyclopropanation is capable of discriminating between alkenes of similar ele...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Royal Society of Chemistry
2018
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5890799/ https://ncbi.nlm.nih.gov/pubmed/29675205 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04861k |
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