NHC and nucleophile chelation effects on reactive iron(ii) species in alkyl–alkyl cross-coupling

While iron–NHC catalysed cross-couplings have been shown to be effective for a wide variety of reactions (e.g. aryl–aryl, aryl–alkyl, alkyl–alkyl), the nature of the in situ formed and reactive iron species in effective catalytic systems remains largely undefined. In the current study, freeze-trappe...

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Vydáno v:Chem Sci
Hlavní autoři: Fleischauer, Valerie E., Muñoz III, Salvador B., Neate, Peter G. N., Brennessel, William W., Neidig, Michael L.
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5890793/
https://ncbi.nlm.nih.gov/pubmed/29675234
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04750a
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