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Solvent exchange in preformed photocatalyst-donor precursor complexes determines efficiency

In homogeneous photocatalytic reduction of CO(2), it is widely assumed that the primary electron transfer from the sacrificial donor to the catalyst is diffusion controlled, thus little attention has been paid to optimizing this step. We present spectroscopic evidence that the precursor complex is p...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Kiefer, Laura M., Kubarych, Kevin J.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5887230/
https://ncbi.nlm.nih.gov/pubmed/29675196
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04533f
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