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Ligand-enabled ortho-C–H olefination of phenylacetic amides with unactivated alkenes

Although chelation-assisted C–H olefination has been intensely investigated, Pd(ii)-catalyzed C–H olefination reactions are largely restricted to acrylates and styrenes. Here we report a quinoline-derived ligand that enables the Pd(ii)-catalyzed olefination of the C(sp(2))–H bond with simple aliphat...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Lu, Ming-Zhu, Chen, Xing-Rong, Xu, Hui, Dai, Hui-Xiong, Yu, Jin-Quan
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5887099/
https://ncbi.nlm.nih.gov/pubmed/29675177
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04827k
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