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Enantiomeric resolution and X-ray optical activity of a tricobalt extended metal atom chain
A simple procedure based on anion exchange was employed for the enantiomeric resolution of the extended metal atom chain (EMAC) [Co(3)(dpa)(4)(MeCN)(2)](2+). Use of the chiral salt (NBu(4))(2)[As(2)(tartrate)(2)], (Λ-1 or Δ-1), resulted in the selective crystallization of the EMAC enantiomers as [Δ-...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5884025/ https://ncbi.nlm.nih.gov/pubmed/29675158 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04131d |
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