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Polarisation effects on the solvation properties of alcohols

Alcohol solvents are significantly more polar than expected based on the measured H-bonding properties of monomeric alcohols in dilute solution. Self-association of alcohols leads to formation of cyclic aggregates and linear polymeric chains that have a different polarity from the alcohol monomer. C...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Henkel, Stefan, Misuraca, Maria Cristina, Troselj, Pavle, Davidson, Jonathan, Hunter, Christopher A.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2017
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5875020/
https://ncbi.nlm.nih.gov/pubmed/29629077
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04890d
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