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Selective Catalytic Oxidation of Cyclohexene with Molecular Oxygen: Radical Versus Nonradical Pathways

We study the allylic oxidation of cyclohexene with O(2) under mild conditions in the presence of transition‐metal catalysts. The catalysts comprise nanometric metal oxide particles supported on porous N‐doped carbons (M/N:C, M=V, Cr, Fe, Co, Ni, Cu, Nb, Mo, W). Most of these metal oxides give only m...

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Publicat a:ChemCatChem
Autors principals: Denekamp, Ilse M., Antens, Martijn, Slot, Thierry K., Rothenberg, Gadi
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5873426/
https://ncbi.nlm.nih.gov/pubmed/29610628
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.201701538
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