Structural and Mechanistic Analysis of the Choline Sulfatase from Sinorhizobium melliloti: A Class I Sulfatase Specific for an Alkyl Sulfate Ester

Hydrolysis of organic sulfate esters proceeds by two distinct mechanisms, water attacking at either sulfur (S–O bond cleavage) or carbon (C–O bond cleavage). In primary and secondary alkyl sulfates, attack at carbon is favored, whereas in aromatic sulfates and sulfated sugars, attack at sulfur is pr...

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Detalhes bibliográficos
Publicado no:J Mol Biol
Main Authors: van Loo, Bert, Schober, Markus, Valkov, Eugene, Heberlein, Magdalena, Bornberg-Bauer, Erich, Faber, Kurt, Hyvönen, Marko, Hollfelder, Florian
Formato: Artigo
Idioma:Inglês
Publicado em: Elsevier 2018
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5870055/
https://ncbi.nlm.nih.gov/pubmed/29458126
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmb.2018.02.010
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