The Lewis superacid Al[N(C(6)F(5))(2)](3) and its higher homolog Ga[N(C(6)F(5))(2)](3) – structural features, theoretical investigation and reactions of a metal amide with higher fluoride ion affinity than SbF(5)

Herein we present the synthesis of the two Lewis acids Al[N(C(6)F(5))(2)](3) (ALTA) and Ga[N(C(6)F(5))(2)](3) (GATA) via salt elimination reactions. The metal complexes were characterized by NMR-spectroscopic methods and X-ray diffraction analysis revealing the stabilization of the highly Lewis acid...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Kögel, J. F., Sorokin, D. A., Khvorost, A., Scott, M., Harms, K., Himmel, D., Krossing, I., Sundermeyer, J.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5869307/
https://ncbi.nlm.nih.gov/pubmed/29629094
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03988c
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