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Mechanically induced pyrogallol[4]arene hexamer assembly in the solid state extends the scope of molecular encapsulation

Pyrogallol[4]arene hexamers are hydrogen-bonded molecular capsules of exceptional kinetic stability that can entrap small molecule guests indefinitely, without exchange, at ambient temperatures. Here, we report on the use of a ball mill to induce self-assembly of the capsule components and the guest...

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Publicado en:Chem Sci
Main Authors: Journey, Sara N., Teppang, Kristine L., Garcia, Cesar A., Brim, Shaylyn A., Onofrei, David, Addison, J. Bennett, Holland, Gregory P., Purse, Byron W.
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5853268/
https://ncbi.nlm.nih.gov/pubmed/29568437
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03821f
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