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Nickel-Catalyzed Asymmetric Reductive Cross-Coupling to Access 1,1-Diarylalkanes

An asymmetric Ni-catalyzed reductive cross-coupling of (hetero)aryl iodides and benzylic chlorides has been developed to prepare enantioenriched 1,1-diarylalkanes. As part of these studies, a new chiral bioxazoline ligand, 4-heptyl-BiOX (L1), was developed in order to obtain products in syntheticall...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Poremba, Kelsey E., Kadunce, Nathaniel T., Suzuki, Naoyuki, Cherney, Alan H., Reisman, Sarah E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5851002/
https://ncbi.nlm.nih.gov/pubmed/28406620
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01705
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