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Pd-catalyzed versus uncatalyzed, PhI(OAc)(2)-mediated cyclization reactions of N(6)-([1,1’-biaryl]-2-yl)adenine nucleosides

In this work we have assessed reactions of N(6)-([1,1’-biaryl]-2-yl)adenine nucleosides with Pd(OAc)(2) and PhI(OAc)(2), via a Pd(II)/Pd(IV) redox cycle. The substrates are readily obtained by Pd/Xantphos-catalyzed reaction of adenine nucleosides with 2-bromo-1,1’-biaryls. In PhMe, the N(6)-biarylyl...

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Publicat a:ChemCatChem
Autors principals: Satishkumar, Sakilam, Poudapally, Suresh, Vuram, Prasanna K., Gurram, Venkateshwarlu, Pottabathini, Narender, Sebastian, Dellamol, Yang, Lijia, Pradhan, Padmanava, Lakshman, Mahesh K.
Format: Artigo
Idioma:Inglês
Publicat: 2017
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5830157/
https://ncbi.nlm.nih.gov/pubmed/29503672
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.201700918
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