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Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp(3))–H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates
A novel mild, visible-light-induced palladium-catalyzed hydrogen atom translocation/atom-transfer radical cyclization (HAT/ATRC) cascade has been developed. This protocol involves a 1,5-HAT process of previously unknown hybrid vinyl palladium radical intermediates, thus leading to iodomethyl carbo-...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5829020/ https://ncbi.nlm.nih.gov/pubmed/29341489 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201712775 |
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