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Multimetallic Ni- and Pd-Catalyzed Cross-Electrophile Coupling to Form Highly Substituted 1,3-Dienes

The synthesis of highly substituted 1,3-dienes from the coupling of vinyl bromides with vinyl triflates is reported for the first time. The coupling is catalyzed by a combination of (5,5’-bis(trifluoromethyl)-2,2’-bipyridine)NiBr(2) and (1,3-bis(diphenylphosphino)propane)PdCl(2) in the presence of a...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Olivares, Astrid M., Weix, Daniel J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5821523/
https://ncbi.nlm.nih.gov/pubmed/29420028
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b13601
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