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Synthesis of Trifluoroacetyl‐Substituted Cyclopropanes Using Onium Ylides

The use of carbonyl‐stabilized ammonium‐ and sulfonium ylides allows for the synthesis of highly‐functionalized trifluoroacetyl‐substituted cyclopropanes. It turned out that the diastereoselectivities strongly depend on the nature of the chosen ylide and the employed base. The products could be obta...

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Pubblicato in:European J Org Chem
Autori principali: Winter, Michael, Gaunersdorfer, Christina, Roiser, Lukas, Zielke, Katharina, Monkowius, Uwe, Waser, Mario
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5817241/
https://ncbi.nlm.nih.gov/pubmed/29491744
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201701699
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