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Improved Description of Sulfur Charge Anisotropy in OPLS Force Fields. Model Development and Parameterization

The atomic point-charge model used in most molecular mechanics force fields does not represent well the electronic anisotropy that is featured in many directional non-covalent interactions. Sulfur participates in several types of such interactions with its lone pairs and σ-holes. The current study d...

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Pubblicato in:J Phys Chem B
Autori principali: Yan, Xin Cindy, Robertson, Michael J., Tirado-Rives, Julian, Jorgensen, William L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2017
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5816952/
https://ncbi.nlm.nih.gov/pubmed/28627890
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.7b04233
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