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Binding of Hydrophobic Guests in a Coordination Cage Cavity is Driven by Liberation of “High‐Energy” Water
The cavity of an M(8)L(12) cubic coordination cage can accommodate a cluster of ten water molecules in which the average number of hydrogen bonds per water molecule is 0.5 H‐bonds less than it would be in the bulk solution. The presence of these “hydrogen‐bond frustrated” or “high‐energy” water mole...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5814853/ https://ncbi.nlm.nih.gov/pubmed/29083066 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201704163 |
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