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Mechanism of supplemental activator and reducing agent atom transfer radical polymerization mediated by inorganic sulfites: experimental measurements and kinetic simulations()
The mechanism of atom transfer radical polymerization (ATRP) mediated by sodium dithionite (Na(2)S(2)O(4)), with Cu(II)Br(2)/Me(6)TREN as catalyst (Me(6)TREN: tris[2-(dimethylamino)ethyl]amine) in ethanol/water mixtures, was investigated experimentally and by kinetic simulations. A kinetic model was...
Shranjeno v:
| izdano v: | Polym Chem |
|---|---|
| Main Authors: | , , , , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2017
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5814143/ https://ncbi.nlm.nih.gov/pubmed/29422955 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7py01319a |
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