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Highly enantioselective access to diketopiperazines via cinchona alkaloid catalyzed Michael additions
Michael addition reactions of triketopiperazine (TKP) derivatives to enones, mediated by a cinchona alkaloid-derived catalyst, deliver products in high yield and enantiomeric ratio (er). Use of unsaturated ester, nitrile or sulfone partners gives bridged hydroxy-diketopiperazine (DKP) products resul...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5811140/ https://ncbi.nlm.nih.gov/pubmed/29560222 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03218g |
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