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The boron–boron triple bond? A thermodynamic and force field based interpretation of the N-heterocyclic carbene (NHC) stabilization procedure
Recently, the NHC→B[triple bond, length as m-dash]B←NHC molecule 1 has been published in Science where it is described as a stabilized B(2) molecule in its (1)Σ excited state (B(2)*) (NHC = N-heterocyclic carbene C(3)N(2)H(2)(C(6)H(3)Pr(i)(2)-2,6)(2)). The bonding of 1 based on sophisticated calcula...
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| Publicado no: | Chem Sci |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5811121/ https://ncbi.nlm.nih.gov/pubmed/29560205 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02997f |
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