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The boron–boron triple bond? A thermodynamic and force field based interpretation of the N-heterocyclic carbene (NHC) stabilization procedure

Recently, the NHC→B[triple bond, length as m-dash]B←NHC molecule 1 has been published in Science where it is described as a stabilized B(2) molecule in its (1)Σ excited state (B(2)*) (NHC = N-heterocyclic carbene C(3)N(2)H(2)(C(6)H(3)Pr(i)(2)-2,6)(2)). The bonding of 1 based on sophisticated calcula...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Chem Sci
Hauptverfasser: Köppe, R., Schnöckel, H.
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2015
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5811121/
https://ncbi.nlm.nih.gov/pubmed/29560205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02997f
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