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Analogies between Vanadoborates and Planar Aromatic Hydrocarbons: A High-Spin Analogue of Aromaticity
The vanadium-vanadium interactions in the polygonal aggregates of d(1) vanadium(IV) atoms, with a total of 4k + 2 vanadium electrons (k an integer) imbedded in an electronically inactive borate matrix in certain vanadoborate structures are analogous to the ring carbon-carbon interactions in diamagne...
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| Publicado no: | Materials (Basel) |
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| Autor principal: | |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5793513/ https://ncbi.nlm.nih.gov/pubmed/29295480 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma11010015 |
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