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Synthesis of Conformationally-Locked cis- and trans-Bicyclo[4.4.0] Mono-, Di- and Trioxadecane Modifications of Galacto- and Glucopyranose. Experimental Limiting (3)J(H,H) Coupling Constants for the Estimation of Carbohydrate Side Chain Populations and Beyond
Hexopyranose side chains populate three staggered conformations, whose proportions can be determined from the three sets of ideal limiting (3)J(H5,H6R) and (3)J(H5,H6S) coupling constants in combination with the time-averaged experimental coupling constants. Literature values for the limiting coupli...
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| Udgivet i: | J Org Chem |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5775050/ https://ncbi.nlm.nih.gov/pubmed/29241001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b02891 |
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