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Aminomethylation of Aryl Halides using α-Silylamines Enabled by Ni/Photoredox Dual Catalysis

A protocol for the aminomethylation of aryl halides using α-silylamines via Ni/photoredox dual catalysis is described. The low oxidation potential of these silylated species enables facile single electron transfer (SET) oxidation of the amine followed by rapid desilylation. The resulting α-amino rad...

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Bibliografski detalji
Izdano u:ACS Catal
Glavni autori: Remeur, Camille, Kelly, Christopher B., Patel, Niki R., Molander, Gary A.
Format: Artigo
Jezik:Inglês
Izdano: 2017
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5771658/
https://ncbi.nlm.nih.gov/pubmed/29354317
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b01973
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