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Cobalt‐Catalyzed Suzuki Biaryl Coupling of Aryl Halides

Readily accessed cobalt pre‐catalysts with N‐heterocyclic carbene ligands catalyze the Suzuki cross‐coupling of aryl chlorides and bromides with alkyllithium‐activated arylboronic pinacolate esters. Preliminary mechanistic studies indicate that the cobalt species is reduced to Co(0) during the react...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Asghar, Soneela, Tailor, Sanita B., Elorriaga, David, Bedford, Robin B.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2017
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5767760/
https://ncbi.nlm.nih.gov/pubmed/29135071
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201710053
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