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Oxidation of Vicinal Diols to α‐Hydroxy Ketones with H(2)O(2) and a Simple Manganese Catalyst

α‐Hydroxy ketones are valuable synthons in organic chemistry. Here we show that oxidation of vic‐diols to α‐hydroxy ketones with H(2)O(2) can be achieved with an in situ prepared catalyst based on manganese salts and pyridine‐2‐carboxylic acid. Furthermore the same catalyst is effective in alkene ep...

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Vydáno v:European J Org Chem
Hlavní autoři: Mecozzi, Francesco, Dong, Jia Jia, Saisaha, Pattama, Browne, Wesley R.
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2017
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5767754/
https://ncbi.nlm.nih.gov/pubmed/29398954
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201701314
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