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Auto‐Tandem Catalysis: Pd(II)‐Catalysed Dehydrogenation/Oxidative Heck Reaction of Cyclopentane‐1,3‐diones

A Pd(II) catalyst system has been used to successfully catalyse two mechanistically distinct reactions in a one‐pot procedure: dehydrogenation of 2,2‐disubstituted cyclopentane‐1,3‐diones and the subsequent oxidative Heck coupling. This auto‐tandem catalytic reaction is applicable to both batch and...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Lamb, Claire J. C., Nderitu, Bryan G., McMurdo, Gemma, Tobin, John M., Vilela, Filipe, Lee, Ai‐Lan
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5767738/
https://ncbi.nlm.nih.gov/pubmed/29105890
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201704442
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