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Kinetics of the Strain-Promoted Oxidation-Controlled Cycloalkyne-1,2-quinone Cycloaddition: Experimental and Theoretical Studies
[Image: see text] Stimulated by its success in both bioconjugation and surface modification, we studied the strain-promoted oxidation-controlled cycloalkyne–1,2-quinone cycloaddition (SPOCQ) in three ways. First, the second-order rate constants and activation parameters (ΔH(⧧)) were determined of va...
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| 發表在: | J Org Chem |
|---|---|
| Main Authors: | , , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
American Chemical
Society
2017
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| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5759032/ https://ncbi.nlm.nih.gov/pubmed/29260879 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b02614 |
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