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Peroxide Activation Regulated by Hydrogen Bonds within Artificial Cu Proteins

Cu-hydroperoxido species (Cu(II)–OOH) have been proposed to be key intermediates in biological and synthetic oxidations. Using biotin-streptavidin (Sav) technology, artificial copper proteins have been developed to stabilize a Cu(II)–OOH complex in solution and in crystallo. Stability is achieved be...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Mann, Samuel I., Heinisch, Tillmann, Ward, Thomas R., Borovik, AS
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5747327/
https://ncbi.nlm.nih.gov/pubmed/29117678
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b10452
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