Metal–Organic Frameworks Invert Molecular Reactivity: Lewis Acidic Phosphonium Zwitterions Catalyze the Aldol-Tishchenko Reaction

[Image: see text] The influence of metal–organic frameworks (MOFs) as additives is herein described for the reaction of n-alkyl aldehydes in the presence of methylvinylketone and triphenylphosphine. In the absence of a MOF, the expected Morita–Baylis–Hillman product, a β-hydroxy enone, is observed....

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Bauer, Gerald, Ongari, Daniele, Xu, Xiaoying, Tiana, Davide, Smit, Berend, Ranocchiari, Marco
Format: Artigo
Language:Inglês
Published: American Chemical Society 2017
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5742478/
https://ncbi.nlm.nih.gov/pubmed/29198106
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b10928
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