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Selective Activation of C−H Bonds in a Cascade Process Combining Photochemistry and Biocatalysis

Selective oxyfunctionalizations of inert C−H bonds can be achieved under mild conditions by using peroxygenases. This approach, however, suffers from the poor robustness of these enzymes in the presence of hydrogen peroxide as the stoichiometric oxidant. Herein, we demonstrate that inorganic photoca...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Zhang, Wuyuan, Burek, Bastien O., Fernández‐Fueyo, Elena, Alcalde, Miguel, Bloh, Jonathan Z., Hollmann, Frank
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5725739/
https://ncbi.nlm.nih.gov/pubmed/28994504
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708668
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