Metallo‐Supramolecular Gels that are Photocleavable with Visible and Near‐Infrared Irradiation

A photolabile ruthenium‐based complex, [Ru(bpy)(2)(4AMP)(2)](PF(6))(2), (4AMP=4‐(aminomethyl)pyridine) is incorporated into polyurea organo‐ and hydrogels via the reactive amine moieties on the photocleavable 4AMP ligands. While showing long‐term stability in the dark, cleavage of the pyridine–ruthe...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Theis, Sabrina, Iturmendi, Aitziber, Gorsche, Christian, Orthofer, Marco, Lunzer, Markus, Baudis, Stefan, Ovsianikov, Aleksandr, Liska, Robert, Monkowius, Uwe, Teasdale, Ian
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5725706/
https://ncbi.nlm.nih.gov/pubmed/28941025
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201707321
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