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Energy decomposition analysis of single bonds within Kohn–Sham density functional theory

An energy decomposition analysis (EDA) for single chemical bonds is presented within the framework of Kohn–Sham density functional theory based on spin projection equations that are exact within wave function theory. Chemical bond energies can then be understood in terms of stabilization caused by s...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Levine, Daniel S., Head-Gordon, Martin
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5715786/
https://ncbi.nlm.nih.gov/pubmed/29158379
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1715763114
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