A Lewis Base Catalysis Approach for the Photoredox Activation of Boronic Acids and Esters

We report herein the use of a dual catalytic system comprising a Lewis base catalyst such as quinuclidin‐3‐ol or 4‐dimethylaminopyridine and a photoredox catalyst to generate carbon radicals from either boronic acids or esters. This system enabled a wide range of alkyl boronic esters and aryl or alk...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Lima, Fabio, Sharma, Upendra K., Grunenberg, Lars, Saha, Debasmita, Johannsen, Sandra, Sedelmeier, Joerg, Van der Eycken, Erik V., Ley, Steven V.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2017
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5708277/
https://ncbi.nlm.nih.gov/pubmed/29024307
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201709690
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