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Adapting the Glaser Reaction for Bioconjugation: Robust Access to Structurally Simple, Rigid Linkers
The copper-mediated coupling between alkynes to generate a structurally rigid, linear 1,3-diyne linkage has been known for over a century. However, the mechanistic requirement to simultaneously maintain Cu(I) and an oxidant has limited its practical utility, especially for complex functional molecul...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5708120/ https://ncbi.nlm.nih.gov/pubmed/28685936 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705065 |
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