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Mechanism of the cooperative Si–H bond activation at Ru–S bonds
The nature of the hydrosilane activation mediated by ruthenium(ii) thiolate complexes of type [(R(3)P)Ru(SDmp)](+)[BAr(F)(4)](–) is elucidated by an in-depth experimental and theoretical study. The combination of various ruthenium(ii) thiolate complexes and tertiary hydrosilanes under variation of t...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Royal Society of Chemistry
2015
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5707498/ https://ncbi.nlm.nih.gov/pubmed/29218203 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01035g |
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