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Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold

Gold-catalyzed intermolecular alkyne oxidation by an N–O bond oxidant has proven to be a powerful method in organic synthesis during the past decade, because this approach would enable readily available alkynes as precursors in generating α-oxo gold carbenes. Among those, gold-catalyzed oxidative cy...

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Publicat a:Nat Commun
Autors principals: Shen, Wen-Bo, Sun, Qing, Li, Long, Liu, Xin, Zhou, Bo, Yan, Juan-Zhu, Lu, Xin, Ye, Long-Wu
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2017
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5701061/
https://ncbi.nlm.nih.gov/pubmed/29170497
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-017-01853-1
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