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Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation

A highly diastereoselective carbon–carbon bond-forming reaction involving the tandem coupling of benzyltriboronates, enoates, and alkyl halides is described. This method was enabled by the discovery of α-diimine nickel catalysts that promote the chemoselective triborylation of benzylic C(sp(3))–H bo...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Palmer, W. Neil, Zarate, Cayetana, Chirik, Paul J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5697753/
https://ncbi.nlm.nih.gov/pubmed/28156108
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b12896
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