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Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation

A highly diastereoselective carbon–carbon bond-forming reaction involving the tandem coupling of benzyltriboronates, enoates, and alkyl halides is described. This method was enabled by the discovery of α-diimine nickel catalysts that promote the chemoselective triborylation of benzylic C(sp(3))–H bo...

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Bibliografische gegevens
Gepubliceerd in:J Am Chem Soc
Hoofdauteurs: Palmer, W. Neil, Zarate, Cayetana, Chirik, Paul J.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2017
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5697753/
https://ncbi.nlm.nih.gov/pubmed/28156108
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b12896
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