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Single-Site Photocatalytic H(2) Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts
[Image: see text] We demonstrate photocatalytic hydrogen evolution using COF photosensitizers with molecular proton reduction catalysts for the first time. With azine-linked N2-COF photosensitizer, chloro(pyridine)cobaloxime co-catalyst, and TEOA donor, H(2) evolution rate of 782 μmol h(–1) g(–1) an...
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| 出版年: | J Am Chem Soc |
|---|---|
| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American Chemical
Society
2017
|
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5691321/ https://ncbi.nlm.nih.gov/pubmed/29022345 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b07489 |
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