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Origins of high catalyst loading in copper(i)-catalysed Ullmann–Goldberg C–N coupling reactions

A mechanistic investigation of Ullmann–Goldberg reactions using soluble and partially soluble bases led to the identification of various pathways for catalyst deactivation through (i) product inhibition with amine products, (ii) by-product inhibition with inorganic halide salts, and (iii) ligand exc...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Sherborne, Grant J., Adomeit, Sven, Menzel, Robert, Rabeah, Jabor, Brückner, Angelika, Fielding, Mark R., Willans, Charlotte E., Nguyen, Bao N.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5688446/
https://ncbi.nlm.nih.gov/pubmed/29147546
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02859h
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