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Photoredox Enables the Construction of 1,1-Difluoroalkene Carbonyl Mimics
We describe a facile, scalable route to access functional group-rich gem-difluoroalkenes. Using visible-light activated catalysts in conjunction with an arsenal of carbon-radical precursors, an array of trifluoromethyl-substituted alkenes undergoes radical defluorinative alkylation. Non-stabilized p...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5688010/ https://ncbi.nlm.nih.gov/pubmed/28960656 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201709487 |
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