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A Highly Efficient Synthesis of Z-Macrocycles using Stereoretentive, Ruthenium-Based Metathesis Catalysts

A highly efficient, Z-selective ring-closing metathesis system for the formation of macrocycles using a stereoretentive, ruthenium-based catalyst supported by a dithiolate ligand is reported. This catalyst is demonstrated to be remarkably active as observed in initiation experiments showing complete...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Ahmed, Tonia S., Grubbs, Robert H.
Format: Artigo
Idioma:Inglês
Publicat: 2017
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5683173/
https://ncbi.nlm.nih.gov/pubmed/28644909
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704670
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