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Unstrained C–C bond activation and directed fluorination through photocatalytically-generated radical cations

Expanding the repertoire of controlled radical fluorination techniques, we present a photosensitized unstrained C–C bond activation/directed monofluorination method using Selectfluor and 9-fluorenone. The reaction is amenable to the opening of multiple 1-acetal-2-aryl substituted rings to yield ω-fl...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Pitts, Cody Ross, Bloom, Michelle Sheanne, Bume, Desta Doro, Zhang, Qinze Arthur, Lectka, Thomas
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5669245/
https://ncbi.nlm.nih.gov/pubmed/29449927
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01973g
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