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Cycloaddition of cyclobutenone and azomethine imine enabled by chiral isothiourea organic catalysts
The addition of an organic catalyst to the ketone moiety of a γ-mono-chloride substituted cyclobutenone destroys its stable, conjugated and nearly planar structure. The C–C bond in the resulting less stable anionic oxy-substituted non-planar intermediate is then activated. The breaking of one C–C si...
Gorde:
| Argitaratua izan da: | Chem Sci |
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| Egile Nagusiak: | , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
Royal Society of Chemistry
2015
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5669243/ https://ncbi.nlm.nih.gov/pubmed/29449914 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01972a |
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