Two New Sandwich-Type Polyoxomolybdates Functionalized with Diphosphonates: Efficient and Selective Oxidation of Sulfides to Sulfones

Two sandwich-type polyoxomolybdates Na(8)[MO(2){Mo(2)O(5)(O(3)PCH(3)C(O)PO(3))}(2)] (M = Ni(2+) (1); Co(2+) (2)) were synthesized by one-pot reaction of Na(2)HPMo(12)O(40)·14H(2)O, 1-hydroxy ethidene diphosphonic acid (HEDP=HOC(CH(3))(PO(3)H(2))(2)), and (1) NiCl(2)/CoCl(2) (2). Compounds 1 and 2 we...

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Vydáno v:Materials (Basel)
Hlavní autoři: Xu, Qiaofei, Sun, Xiaopeng, Hu, Feng, Wan, Rong, Singh, Vikram, Ma, Pengtao, Niu, Jingyang, Wang, Jingping
Médium: Artigo
Jazyk:Inglês
Vydáno: MDPI 2017
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5666979/
https://ncbi.nlm.nih.gov/pubmed/29027947
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma10101173
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