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Palladium(0) NHC complexes: a new avenue to highly efficient phosphorescence

We report the first examples of highly luminescent di-coordinated Pd(0) complexes. Five complexes of the form [Pd(L)(L′)] were synthesized, where L = IPr, SIPr or IPr* NHC ligands and L′ = PCy(3), or IPr and SIPr NHC ligands. The photophysical properties of these complexes were determined in degasse...

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Publicat a:Chem Sci
Autors principals: Henwood, Adam F., Lesieur, Mathieu, Bansal, Ashu K., Lemaur, Vincent, Beljonne, David, Thompson, David G., Graham, Duncan, Slawin, Alexandra M. Z., Samuel, Ifor D. W., Cazin, Catherine S. J., Zysman-Colman, Eli
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2015
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5657412/
https://ncbi.nlm.nih.gov/pubmed/29142691
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03914a
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