An Icosidodecahedral Supramolecule Based on Pentaphosphaferrocene: From a Disordered Average Structure to Individual Isomers

Pentaphosphaferrocenes [Cp(R)Fe(η(5)‐P(5))] (1) and Cu(I) halides are excellent building blocks for the formation of discrete supramolecules. Herein, we demonstrate the potential of Cu(CF(3)SO(3)) for the construction of the novel 2D polymer [{Cp*Fe(μ(4),η(5:1:1:1)‐P(5))}{Cu(CF(3)SO(3))}](n) (2) and...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Heindl, Claudia, Peresypkina, Eugenia, Virovets, Alexander V., Bushmarinov, Ivan S., Medvedev, Michael G., Krämer, Barbara, Dittrich, Birger, Scheer, Manfred
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5656825/
https://ncbi.nlm.nih.gov/pubmed/28793182
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706756
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