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Gold(i)-catalyzed [2 + 2 + 2] cycloaddition of allenamides, alkenes and aldehydes: a straightforward approach to tetrahydropyrans

Allenamides participate as two-carbon components in an intermolecular [2 + 2 + 2] cycloaddition with alkenes and aldehydes when treated with catalytic amounts of a phosphite gold complex. The reaction is highly regio- and chemoselective, and works with different types of alkenes, including styrenes,...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Faustino, Hélio, Varela, Iván, Mascareñas, José L., López, Fernando
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5655898/
https://ncbi.nlm.nih.gov/pubmed/29308168
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00295h
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