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Manganese(II) complexes with Bn-tpen as powerful catalysts of cyclohexene oxidation

Manganese(II) complex [(Bn-tpen)Mn(II)](2+) activated dioxygen for oxidation of cyclohexene in acetonitrile (MeCN) and methanol (MeOH). In MeCN, ketone (2-cyclohexen-1-one), alcohol (2-cyclohexen-1-ol) and small amounts of epoxide (cyclohexene oxide) were produced in this reaction, while in MeOH onl...

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Detalhes bibliográficos
Publicado no:Chem. Zvesti
Main Authors: Rydel-Ciszek, Katarzyna, Charczuk, Maria, Pacześniak, Tomasz, Chmielarz, Paweł
Formato: Artigo
Idioma:Inglês
Publicado em: Springer International Publishing 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5655609/
https://ncbi.nlm.nih.gov/pubmed/29104351
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s11696-017-0201-0
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